自然科学版
陕西师范大学学报(自然科学版)
化学与材料科学
气相原位反应制备表面负载纳米银PAM复合微球
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宋少飞1, 周福林1, 弓巧娟1, 韩秋萍1, 沈淑坤2
(1 运城学院 应用化学系, 山西 运城 044000;2 陕西师范大学 化学化工学院, 陕西 西安 710062)
宋少飞,男,讲师,博士,主要从事功能高分子材料的制备及应用研究.E-mail:ssfzfl@163.com.
摘要:
采用反相悬浮聚合法合成了聚丙烯酰胺(PAM)高分子微凝胶,以PAM微凝胶为微反应器,通过气相原位还原,利用甲醛与银氨溶液的银镜反应,制得了表面担载银纳米粒子的微米级Ag/PAM复合微球.利用SEM、XRD和TGA等手段对复合微球进行了形貌和组分表征.结果表明:该复合微球具有规则的表面图案化形貌和核-壳结构,并具有内亲水外疏水的特性,银纳米粒子担载量大约为8.52%.
关键词:
聚丙烯酰胺微凝胶; 银; 复合微球; 气相原位反应
收稿日期:
2012-11-25
中图分类号:
O631.1
文献标识码:
文章编号:
1672-4291(2013)03-0036-04
基金项目:
国家自然科学基金青年科学基金资助项目(21103103); 运城学院产学研合作研究资助项目(CY-2012020,CY-2012019)
Doi:
Preparation of Ag/PAM composite microspheres by the in-situ gas phase reaction
SONG Shao-fei1, ZHOU Fu-lin1, GONG Qiao-juan1, HAN Qiu-ping1, SHEN Shu-kun2
(1 Department of Applied Chemistry, Yuncheng University, Yuncheng 044000,Shanxi,China; 2 College of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi′an 710062, Shaanxi,China)
Abstract:
Polylacrylamide (PAM) microspheres were prepared by reverse suspension polymerization,and then the composite Ag/PAM microspheres loaded with silver nanoparticles were obtained by silver mirror reaction with formaldehyde as reductant in atmosphere. The composition and morphology of the composite microspheres were investigated by SEM, XRD and TGA, respectively. The results indicated that the surface of composite microspheres has uniform pattern morphology with PAM microgel core and silver shell structure. Additionally, the composite microspheres have internal hydrophilicity and external hydrophobicity characters. The loading quantity of silver nanoparticles on PAM microspheres is about 8.52%.
KeyWords:
PAM microhydrogel; silver; composite microspheres; the gas phase reaction in-site