自然科学版
陕西师范大学学报(自然科学版)
物理学
Mn/ZnS量子点的制备及表征
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渠莉华, 王公正*, 张建民
(陕西师范大学 物理学与信息技术学院,陕西 西安 710062)
渠莉华,女,博士研究生,主要研究方向为高分子复合材料.E-mail:qulihua05@163.com.*通信作者: 王公正,男,副教授.E-mail:gongzhw@snnu.edu.cn.
摘要:
为了得到晶型稳定、荧光性可控的Mn/ZnS量子点,用锰、锌、硫的盐溶液进行制备,以X射线衍射、原子吸收光谱、荧光光谱、原子力显微镜扫描等手段进行了表征.利用原子力显微镜可以观察量子点的形貌及分布情况,并能鉴别出Mn2+特殊的形貌结构.结果表明,不同锌硫比条件下的晶面取向稳定,并且锰离子成功掺入了ZnS晶格.不同锌硫比导致发光强度有所不同,在锌硫比为1∶1时,Mn/ZnS发光强度最大.该方法制备出的Mn/ZnS量子点晶型稳定,并且具有可控的荧光性.
关键词:
Mn/ZnS; 量子点; 制备; 表征
收稿日期:
2012-04-15
中图分类号:
O431.2
文献标识码:
A
文章编号:
1672-4291(2013)01-0028-04
基金项目:
国家自然科学基金资助项目(51071098).
Doi:
Preparation and characterization of Mn/ZnS quantum dots
QU Li-hua, WANG Gong-zheng*, ZHANG Jian-min
(College of Physics and Information Technology,Shaanxi Normal University, Xi′an 710062, Shaanxi, China)
Abstract:
In order to get Mn/ZnS quantum dots with stable structures and adjustable fluorescence, the QDs are prepared by solutions of manganese, zinc and sulfur salts. The X-ray diffraction (XRD), atom absorbance system (AAS), fluorescence spectrum and atomic force microscope (AFM) scanning are used to characterize the samples. The morphology is observed by AFM, moreover, the microstructure of manganese can be identified. Our results show that different ratios of Zn and S will induce the difference of luminous intensity and crystal orientations are stable with Mn2+ successfully adding into ZnS crystal. Mn/ZnS nanocrystalline has better luminous properties when Zn∶S is 1∶1. The Mn/ZnS quantum dots made by this method have steady crystal forms and controlled fluorescence.
KeyWords:
Mn/ZnS; quantum dots; preparation; characterization