自然科学版
陕西师范大学学报(自然科学版)
资源与环境科学
陕北延河流域土壤多环芳烃分布特征及来源
PDF下载 ()
李琦1,2,黄廷林2,尚晓青1,薛科社1
(1 西北大学 城市与环境学院, 陕西 西安710127; 2 西安建筑科技大学 环境与市政工程学院, 陕西 西安 710055)
李琦,女,博士研究生,研究方向为环境污染控制及生物修复.E-mail: qili726@ 163.com.
摘要:
采集了陕北延河流域4种土地类型区的16个表层土壤样品,采用GC-MS对美国环境保护局(USEPA)优控的l6种多环芳烃(PAHs)进行含量和组分特征的分析.结果表明:陕北延河流域不同类型土壤中PAHs 的平均质量分数为73.7~ 1 795.4 μg/kg, PAHs 在土壤中的残留特征为井场土壤>公路周边土壤>井场周围土壤>农田土壤,残留水平高的区域处于中等污染水平,部分点位代表区域污染较严重;研究区内PAHs的组分特征是以二环为主的低环组分,PAHs的含量总变化趋势是二环>四环>三环>五环>六环,石油类挥发或泄漏对采油区土壤中PAHs 的累积影响显著.
关键词:
土壤; 多环芳烃; 分布特征; 延河流域
收稿日期:
2011-04-18
中图分类号:
X53
文献标识码:
A
文章编号:
1672-4291(2011)06-0076-05
基金项目:
国家自然科学基金资助项目(50378077); 陕西省教育厅专项基金项目(07JK388).
Doi:
Distribution and sources of polycyclic aromatic hydrocarbon (PAHs) pollutants in soils of Yanhe River basin, north of Shaanxi province
LI Qi1,2,HUANG Ting-lin2,SHANG Xiao-qing1,XUE Ke-she1
(1 College of Urban and Environmental Sciences, Northwest University, Xi′an 710127,Shaanxi, China; 2 School of Environmental and Municipal Engineering, Xi′an University of Architecture &Technology, Xi′an 710055,Shaanxi, China)
Abstract:
On the basis of 16 surface soil samples collected from 4 types of land in the Yanhe River basin, north of Shaanxi province, the concentrations and component characteristics of 16 polycyclic aromatic hydrocarbons (PAHs) which have been being prior controlled by USEPA were analyzed using GC-MS. The results show that the maximum PAHs concentration in all soil samples was 1 795.4 μg/kg with a minimum value of 73.7 μg/kg. For residues of PAHs in the soil, it was characterized by well field soil> soil around road> soil around the well site> agricultural soil. However, the soil pollution with higher residual concentration of PAHs was not serious. The main component of PAHs from soil sample in the study area is mainly formed by two-ring hydrocarbons. In general, the PAHs content in soil ranged as follows: two-ring>four-ring>three-ring >five-ring>six-ring. Evaporation or leakage of oil had a significantly cumulative effect on PAHs in the soil.
KeyWords:
soil; polycyclic aromatic hydrocarbons (PAHs); distribution characteristics; Yanhe River basin