自然科学版
陕西师范大学学报(自然科学版)
物理学
CuO-Li2CO3共掺杂低温烧结Ba0.60Sr0.40TiO3陶瓷的介电性能
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荆慧霞,王亚娟,张瑜,杨敬娜,吴怡,刘成,刘鹏*
(陕西师范大学 物理学与信息技术学院, 陕西 西安 710062)
荆慧霞,女,硕士研究生,研究方向为凝聚态物理及无机非金属材料.E-jinghuixia555@163.com.* 通信作者:刘鹏,男,教授,博士研究生导师.E-mail:liupeng68@hotmail.com.
摘要:
采用传统固相反应法,在低温下制备了Ba0.60Sr0.40TiO3 陶瓷.研究了CuO和Li2CO3共掺杂对Ba0.60Sr0.40TiO3陶瓷烧结行为、相结构、显微组织和介电性能的影响.结果表明:采用02% CuO 和20% Li2CO3共掺杂,能有效将Ba0.6Sr0.4TiO3陶瓷烧结温度从1 350℃降至 925℃,且低温烧结的样品具有良好的介电性能:εr=2 725, tan δ=0.004 4 (10 kHz,20℃), 可调性为322% (10 kHz,2 kV/mm).
关键词:
低温烧结; 介电性能; 相结构
收稿日期:
2011-01-18
中图分类号:
O469; TB333
文献标识码:
A
文章编号:
1672-4291(2011)03-0037-04
基金项目:
国家自然科学基金资助项目(50872078; 50772065).
Doi:
Dielectric properties of low-temperature sintered Ba0.60Sr0.40TiO3 ceramics co-doped with CuO-Li2CO3
JING Hui-xia, WANG Ya-juan, ZHANG Yu, YANG Jing-na, WU Yi, LIU Cheng, LIU Peng*
(College of Physics and Information Technology, Shaanxi Normal University, Xi′an 710062, Shaanxi, China)
Abstract:
Ba0.60Sr0.40TiO3 (BST) ceramic is prepared by the conventional solid state-sintering process at low temperature. The sintering behaviors, phase components, microstructures and the dielectric properties of BST ceramics co-doped with CuO and Li2CO3 is investigated. It indicated that the combination of 0.2% CuO and 2.0% Li2CO3 additions is effective in reducing the sintering temperature of Ba0.60Sr0.40TiO3 ceramics from 1 350℃ down to 925℃ and the sample sintered at low temperature displayed excellent comprehensive dielectric properties: εr=2 725, tan δ=0.004 4 ( measured at 10 kHz and 20℃), and a tunability of 32.2% ( at 10 kHz under a dc electric field of 2 kV/mm ).
KeyWords:
low-temperature sintering; dielectric properties; phase component