自然科学版
陕西师范大学学报(自然科学版)
化学与材料科学
新型8-羟基喹啉衍生物及其金属锌配合物的制备与荧光性能
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李会丽,潘宁,李奇,王晓,徐峰*
(大分子科学陕西省重点实验室, 陕西师范大学 化学与材料科学学院, 陕西 西安 710062)
李会丽,女,硕士研究生,主要研究方向为金属有机化学.* 通信作者:徐峰,男,教授,博士研究生导师.E-mail: xufeng6851@yahoo.com.
摘要:
报道了两种新型8-羟基喹啉衍生物N1, N4-双(5-亚甲基-8-羟基喹啉)-1,4-二胺基苯(A)和4-[4′-(5-甲胺基-8-羟基喹啉)]苄基-N-(5-亚甲基-8-羟基喹啉)苯胺(B)以及它们的金属锌配合物的合成、结构表征和荧光性能.产物经红外光谱(IR)、紫外光谱(UV)、核磁共振氢谱(1H NMR)、元素分析表征,其结构与目标物结构相吻合.荧光测定结果表明,与8-羟基喹啉比较,两种8-羟基喹啉衍生物及其配合物的荧光吸收均发生了明显红移.
关键词:
8-羟基喹啉衍生物;金属配合物;荧光性质
收稿日期:
2010-03-18
中图分类号:
O62632+3
文献标识码:
A
文章编号:
1672-4291(2011)01-0054-06
基金项目:
国家自然科学基金资助项目(20872085).
Doi:
Synthesis and fluorescence properties of two new 8-hydroxyquinoline derivatives and their metal Zinc complexes
LI Hui-li, PAN Ning, LI Qi,WANG Xiao, XU Feng*
(Key Laboratory of Macromolecular Science of Shaanxi Province, College of Chemistry and Materials Science, Shaanxi Normal University, Xi′an 710062, Shaanxi, China)
Abstract:
Synthesis and characterization of two kinds of new 8-hydroxyquinoline derivatives and their metal zinc complexes were described in this paper. All the products were characterized by FTIR, UV, 1H NMR, and their fluorescence properties have been studied . The results show that luminescence wavelength of two 8-hydroxyquinoline derivatives and their metal complexes has a bathochromic shift comparing with 8-hydroxyquinoline.
KeyWords:
8-hydroxyquinoline derivates; metal complex; fluorescence property