自然科学版
陕西师范大学学报(自然科学版)
化学与材料科学
遗址土壤中盐分分布规律探索
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黄四平1,2,李玉虎1*,赵玉杰1
(1 陕西师范大学 化学与材料科学学院, 陕西 西安 710062; 2 咸阳师范学院 化学与化工学院, 陕西 咸阳 712000)
黄四平,男,博士研究生,主要从事黄土遗址防风化研究工作.* 通信作者:李玉虎,男,教授,博士研究生导师.E-mail: liyuhu@snnu.edu.cn.
摘要:
针对陕西师范大学长安校区新开挖土遗址模拟坑出现的析白物病害,使用常规的定性与定量分析方法,测定了距遗址墙壁不同深度和距遗址上表面不同高度可溶盐的成分及其含量;应用XRD和SEM分析了矿物及盐分对遗址土壤结构的破坏作用.结果表明,遗址表面易溶性盐主要成分为氯化钠和盐胀系数较大的硫酸钠,微溶盐为硫酸钙.随着距离遗址表面深度的增加,可溶盐以氯化钠、氯化钾为主,微溶盐硫酸钙的含量很少,且盐分分布与水分运移有很大关系.
关键词:
土遗址; 可溶盐; 微溶盐; 分布; 水分运移
收稿日期:
2010-01-18
中图分类号:
S152.4; K854.3
文献标识码:
A
文章编号:
1672-4291(2010)05-0051-05
基金项目:
陕西省科技攻关项目(2009k01-43);咸阳师范学院专项科研基金项目(08XSYK343).
Doi:
Preliminary study on migration of soluble salts in simulated earthen site
HUANG Si-ping1,2, LI Yu-hu1*,ZHAO Yu-jie1
(1 College of Chemistry and Materials Science, Shaanxi Normal University, Xi′an 710062, Shaanxi, China;2 School of Chemmistry and Engineering, Xianyang Normal University,Xianyang 712000,Shaanxi, China)
Abstract:
To investigate white educt occurred at simulated earthen pit in Shaanxi Normal University, using conventional qualitative and quantitative analysis method, components and contents of soluble salts at different position are analyzed . The surface morphology of the samples are comprehensively measured by XRD and SEM. The results show that the white educts are NaCl and Na2SO4 with big diffusion coefficients, and CaSO4 with slight solubility. With increase of depth, NaCl and KCl are dominant, but content of CaSO4 are little. The results also indicate that the distribution of salts is closely related to water movement. These results provide useful information on conservation of earthen sites.
KeyWords:
earthen sites; soluble salt; micro-solubility salts; distribution; water movement