自然科学版
陕西师范大学学报(自然科学版)
化学与材料科学
层层自组装技术在功能薄膜材料制备中的应用
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刘宗怀,乔山峰,袁佳琦,马向荣,许乃才
(应用表面与胶体化学教育部重点实验室, 陕西师范大学 化学与材料科学学院, 陕西 西安 710062)
刘宗怀,男,教授,主要从事功能材料方面的研究.E-mail: zhliu@snnu.edu.cn.
摘要:
层层自组装技术在材料制备方面具有材料的尺寸、成分和形貌可控等特点,而被广泛应用于功能薄膜材料的制备.以层层自组装过程的作用力(静电作用、氢键、共价键、电荷转移相互作用和配位键等)为出发点,探讨了不同作用力对层层自组装过程的影响,及层层自组装技术在不同形貌(平面薄膜、胶囊、纳米管状等)功能薄膜材料制备上的应用.由于其具有吸附、催化、发光和光电特性等,可望在选择性催化剂、模拟细胞行为、药物缓释、生物传感器、选择性渗透薄膜及电极材料等方面应用.层层自组装技术已成为化学、物理、生物、材料和纳米科学等领域的重要手段.
关键词:
层层自组装; 功能纳米薄膜; 制备技术
收稿日期:
2009-07-16
中图分类号:
TQ050.4+3
文献标识码:
A
文章编号:
1672-4291(2010)04-0065-08
基金项目:
国家863计划基金资助项目(2007AA03Z248)
Doi:
Research on application for fabricating functional thin film materials via layer-by-layer self-assembly technology
LIU Zong-huai, QIAO Shan-feng, YUAN Jia-qi, MA Xiang-rong, XU Nai-cai
(Key Laboratory of Applied Surface and Colloid Chemistry Ministry of Education;College of Chemistry and Materials Science, Shaanxi Normal University, Xi′an 710062, Shaanxi, China)
Abstract:
The layer-by-layer(LBL) technique has been widely used to prepare nanofilm materials with precise control of material size, composition and morphology. Based on the interactions forces (electrostatic force, hydrogen bond, covalent bond, charge-transfer and coordination bond), LBL self-assembly process and the application of LBL self-assembly technology to fabricating thin film materials with various morphologies (planar films, capsules, nanotubes and so on) and functions are reviewed. Due to their distinctive chemical and physical properties including adsorption, catalyses, irradiance and photoelectricity, the functional thin film materials prepared from LBL self-assembly technology have potential applications in the areas of selective catalyst, simulation of cell behavior, drug release, biosensors, permselective membranes and electrode materials. LBL self-assembly technology has become an important method in fields of chemistry, physics, biology, material and nanoscience.
KeyWords:
layer-by-layer self-assembly; functional nanofilm; fabrication technology