自然科学版
陕西师范大学学报(自然科学版)
专题研究
YMnO3掺杂四元系PZT-PFW-PMN压电陶瓷电性能的研究
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王林芳,晁小练,杨祖培
(陕西师范大学 化学与材料科学学院, 陕西 西安 710062)
王林芳,女,讲师,主要从事材料化学方面的研究.
摘要:
用传统固相法制备了PbZrO3-PbTiO3-Pb(Fe2/3W1/3)O3-Pb(Mn1/3Nb2/3)O3(简称PZT-PFW-PMN)四元系压电陶瓷,通过预先合成的方法制备了YMnO3,并研究了不同含量的YMnO3对PZT-PFW-PMN陶瓷的烧结温度、压电性能、介电性能的影响,对其阻抗频谱图进行了分析.结果表明,当YMnO3 的含量为0.30%时,不仅使四元系PZT-PFW-PMN的烧结温度从1 200℃降至1 020 ℃,而且使其具有高的压电综合性能;其电性能参数如下:d33=341 pC/N,Kp=0.574,Qm=139 3,tan δ=0.005 3, Tc=304 ℃,ρ=5.23×1 010 Ωm,该材料可用作大功率多层压电陶瓷器件的候选材料.
关键词:
大功率压电陶瓷; PZT-PFW-PMN; 相结构; 压电性能; 低温烧结
收稿日期:
2007-05-05
中图分类号:
TM282
文献标识码:
A
文章编号:
1672-4291(2007)03-0061-04
基金项目:
陕西省自然科学基金资助项目(2005B16)
Doi:
Electrical properties of quaternary PZT-PFW-PMN piezoelectric ceramics with YMnO3 addition
WANG Lin-fang, CHAO Xiao-lian, YANG Zu-pei
(College of Chemistry and Materials Science, Shaanxi Normal University, Xi′an 710062, Shaanxi, China)
Abstract:
PbZrO3-PbTiO3-Pb(Fe2/3W1/3)O3-Pb(Mn1/3Nb2/3)O3 quaternary piezoelectric ceramics with various YMnO3 contents were successfully prepared by conventional mixed-oxide method. The effects of YMnO3 contents and sintering temperature on the dielectric and piezoelectric properties were investigated. The results show that the sintering temperature can be decreased from 1 200 ℃ to 1 020 ℃ and the electrical properties can be improved by the YMnO3 doping. The optimized properties were obtained by doping 0.30% YMnO3 and sintering at 1 020 ℃, which are listed as follows: d33=341 pc/N, Kp=0.574, Qm=1 393, tan δ=0.005 3,Tc=304 ℃ and ρ=5.23×1010 Ωm. These parameters make this material be a good candidate for application in high power piezoelectric transformers.
KeyWords:
high power piezoelectric transformer; PZT-PFW-PMN; phase structure; piezoelectric properties; low temperature sintering