自然科学版
陕西师范大学学报(自然科学版)
电介质物理和材料专刊
稀土La掺杂对M型锶六角铁氧体电、磁、磁介电行为的影响
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周双,杨阳,雷润宇,周剑平*
(陕西师范大学 物理学与信息技术学院,陕西 西安 710119)
周剑平,男,教授,博士生导师,研究方向为功能磁介电材料。E-mail:zhoujp@snnu.edu.cn
摘要:
采用固相反应法合成了Sr1-xLaxFe12O19(x=0,0.05,0.1和0.15)陶瓷样品。结构分析表明,镧掺杂对样品的晶胞参数能够产生影响,但不会对形貌产生影响。介电性能分析表明,掺杂陶瓷的介电常数比纯SrFe12O19陶瓷有明显提高,但是介电损耗也相对较大,其介电性能主要是由Maxwell-Wagner界面极化效应造成。磁性能分析表明,随着镧掺杂量的增加,饱和磁化强度和矫顽力均有所提高。不同样品发生正负磁介电系数转变的温度有所不同,其中x=0的转变温度在50~75 K温度范围,而x=0.05~0.15的转变温度在25~50 K之间,镧掺杂后陶瓷在75~200 K获得较大的磁介电系数。镧掺杂在提高陶瓷样品介电常数的同时保持陶瓷的磁性能。
关键词:
离子掺杂;M型锶六角铁氧体;介电性能;磁性能;磁介电效应
收稿日期:
2021-04-27
中图分类号:
O487
文献标识码:
A
文章编号:
1672-4291(2021)04-0116-09
基金项目:
国家自然科学基金(51672168);中央高校基本科研业务费创新团队项目(GK201901005);陕西师范大学硕士创新基金(2019CSY005)
Doi:
The effects of rare earth doping on the electrical, magnetic, and magnetodielectricbehaviors of M-type strontium hexaferrites
ZHOU Shuang, YANG Yang, LEI Runyu, ZHOU Jianping*
(School of Physics and Information Technology, Shaanxi Normal University,Xi′an 710119, Shaanxi, China)
Abstract:
Sr1-xLaxFe12O19 (x=0, 0.05, 0.1 and 0.15) ceramics were successfully synthesized by solid state reaction method. La doping can affect the crystal lattice parameters, but it has little effect on the morphology. The dielectric constant of the doped ceramics is significantly higher than that of the pure phase ceramics, but the dielectric loss is relatively large. The dielectric properties of the doped ceramics are mainly caused by the Maxwell-Wagner interface polarization effect. At the same time, the magnetic properties are improved after doping lanthanum ions. The change of the dielectric constant with magnetic field shows that the temperature transition from positive to negative magnetodielectric effect is different. The transition temperature for the pure SrFe12O19 is between 50 and 75 K, and the transition temperature for samples with x=0.05, 0.1 and 0.15 is between 25 and 50 K. The magnetodielectric coefficient is relatively large between 75 and 200 K due to the polarization effect of the Maxwell-Wagner interface, which is an extrinsic phenomenon.The results show that the dielectric constant of La doped ceramics is greatly improved, while the magnetic properties are well maintained.
KeyWords:
ion doping; M-type strontium hexaferrites; dielectric properties; magnetic properties; magnetodielectric effect