自然科学版
陕西师范大学学报(自然科学版)
电介质物理和材料专刊
Zr取代MgTiTa2O8微波介质陶瓷的制备与性能研究
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曾瑞,刘成*,张怀武
(电子科技大学 电子科学与工程学院,四川 成都 610054)
刘成,男,博士,副教授,硕士生导师,主要研究方向为电子信息功能材料与元器件。E-mail: c_liu@uestc.edu.cn
摘要:
MgTiTa2O8微波介质陶瓷具有适中的介电常数以及较高的Q×f值,但其τf值偏大,无法应用到实际的器件中。为改善MgTiTa2O2微波介质陶瓷性能,采用传统固相反应法制备Mg(Ti1-xZrx)Ta2O8(x=0.2,0.4,0.6,0.8)微波介质陶瓷材料,并研究了Zr4+取代Ti4+对MgTiTa2O8微波介质陶瓷微观结构以及微波介电性能的影响。结果发现,随着Zr4+掺杂量的逐渐增加,陶瓷内部结构按以下顺序发生变化:三金红石结构—三金红石结构与锰钨矿结构共存—锰钨矿结构。相比于纯MgTiTa2O8微波介质陶瓷,当x=0.4时,材料的温度系数有所改善,为9.6×10-6/℃。在1 350 ℃烧结温度下获得了MgTi0.6Zr0.4Ta2O8微波介质陶瓷材料,表现出优异的微波介电性能:εr = 31,Q×f=30 544 GHz,τf=9.6×10-6/℃。
关键词:
MgTiTa2O8陶瓷;微波介电性能;三金红石;谐振频率温度系数
收稿日期:
2021-04-16
中图分类号:
O487
文献标识码:
A
文章编号:
1672-4291(2021)04-0091-05
基金项目:
四川省科技计划重点研发项目(2020YFG0108)
Doi:
Preparation and properties of Zr-substituted MgTiTa2O8 microwave dielectric ceramics
ZENG Rui, LIU Cheng*, ZHANG Huaiwu
(School of Electronic Science and Engineering,University of Electronic Science and Technology of China, Chengdu 610054, Sichuan, China)
Abstract:
MgTiTa2O8 microwave dielectric ceramic material has moderate dielectric constant and high Q×f value, but its τf value is too large to be applied in practical devices. Mg(Ti1-xZrx)Ta2O8(x=0.2,0.4,0.6,0.8) microwave dielectric ceramics were prepared by the traditional solid-state reaction method, and the effects of replacing Ti4+ with Zr4+ on the microstructure and microwave dielectric properties of MgTiTa2O8 dielectric ceramics were studied. With the gradual increase of Zr4+ doping, the internal structure of ceramics changes in the following order: tri-rutile structure coexistence of tri-rutile and wolframite structure wolframite structure, and the change of ceramic internal structure will affect the microwave dielectric properties of the materials. Compared with pure MgTiTa2O8 microwave dielectric ceramics, the temperature coefficient of the material is improved to 9.6×10-6 /℃ when x=0.4.MgTi0.6Zr0.4Ta2O8 microwave dielectric ceramics were prepared at the sintering temperature of 1 350 ℃, showing excellent microwave dielectric properties: εr=31,Q×f=30 544 GHz,τf=9.6×10-6/℃.
KeyWords:
MgTiTa2O8 ceramics; microwave dielectric properties; tri-rutile; temperature coefficient of resonance frequency