自然科学版
陕西师范大学学报(自然科学版)
电介质物理和材料专刊
基于冷烧结技术的电介质材料研究进展
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付长利,李晓萌,郭靖*
(西安交通大学 材料科学与工程学院,金属材料强度国家重点实验室,陕西 西安 710049)
郭靖,男,副教授,特聘研究员,博士生导师,主要研究方向为微波介质材料、冷烧结、低温烧结、陶瓷基电子功能材料。E-mail:jingguo19@xjtu.edu.cn
摘要:
冷烧结技术是一种超低温烧结工艺,烧结温度一般低于300 ℃,它使用中间液相(如水、酸性溶液、碱性溶液等)和外部压力来帮助粉末致密化,可有效解决陶瓷材料在界面控制、物相稳定性和复合烧结等方面遇到的困难。本文综述了冷烧结技术的烧结机理和其在电介质材料中的应用,重点阐述了冷烧结技术在微波介质陶瓷、铁电压电陶瓷、陶瓷-有机物、陶瓷-无机添加剂以及多层共烧材料中的应用。冷烧结技术可以实现多种电介质材料的超低温烧结,特别有利于实现不同属性材料的共烧,并且获得传统烧结无法达到的优异性能;但因提出时间较短、烧结机理相对复杂且陶瓷材料体系又非常庞大,冷烧结技术仍然存在巨大的提升空间。
关键词:
冷烧结;电介质材料;电子功能陶瓷;复合材料;多层共烧
收稿日期:
2021-04-15
中图分类号:
TB34
文献标识码:
A
文章编号:
1672-4291(2021)04-0030-13
基金项目:
国家自然科学基金(51902245);陕西省自然科学基础研究计划(2020JQ-044)
Doi:
Recent progress of dielectric materials prepared via cold sintering process
FU Changli, LI Xiaomeng, GUO Jing*
(School of Materials Science and Engineering, State Key Laboratory for Mechanical Behavior of Materials, Xi′an Jiaotong University, Xi′an 710049, Shaanxi, China)
Abstract:
Cold sintering process is an extremely low temperature process, with the sintering temperature typically below 300 ℃, which uses a transient liquid phase (such as water, acid solutions and aqueous alkali) and an applied pressure to assist the densification of ceramic powders. The low sintering temperature and short holding time of cold sintering process can effectively solve the difficulties encountered in the interface control, phase stability and composite sintering. This article mainly introduces the sintering mechanism of cold sintering process and the applications in dielectric materials, focusing on microwave dielectrics, ferroelectrics, piezoelectrics, ceramic based composites and multilayer materials. The cold sintering process has realized the densification of various dielectric materials with good properties at extremely low temperatures, which has greatly promoted the progress and development of low temperature sintering technology. It provides a new route for the development of dielectric materials, and is expected to make a breakthrough in the field of high performance dielectric materials with low CO2 emission. However, it is worth noting that cold sintering process is in the early stage. The sintering mechanism is relatively complex and large varieties of material systems are available, so there is still a lot of room for improvement.
KeyWords:
cold sintering process; dielectric materials; electro-ceramics; composites; multilayers