自然科学版
陕西师范大学学报(自然科学版)
化学与材料科学
改性磷酸盐胶黏剂和环氧树脂胶黏剂在陶质文物粘接中的对比研究
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谢丽娜, 李玉虎*, 王盛霖, 白崇斌
(陕西师范大学 历史文化遗产保护教育部工程研究中心, 陕西 西安 710119)
李玉虎,男,教授,博士生导师,主要从事历史文化遗产保护研究工作。E-mail: liyuhu@snnu.edu.cn
摘要:
研制了一种用于断裂陶质文物粘接的无机改性磷酸盐胶黏剂。实验选取在文物保护中最常用的环氧树脂类胶黏剂作对比,评价了该胶黏剂的性能。采用湿热老化和干热老化两种老化方法,通过测试胶黏剂的粘接强度、微观形貌变化和红外光谱分析其耐老化性能;通过透气性、透水性和SEM测试胶黏剂与文物本体的兼容性。结果表明,无机改性磷酸盐胶黏剂耐老化性能强,与陶质文物本体的兼容性好,是一种新型理想的陶质文物粘接用材料。
关键词:
陶质文物;粘接;胶黏剂;耐老化性;兼容性
收稿日期:
2018-01-22
中图分类号:
K854.3
文献标识码:
A
文章编号:
1672-4291(2019)04-0089-08
基金项目:
国家自然科学基金(51403121)
Doi:
Comparative study of modified phosphate adhesives and epoxy resin adhesive used in repairing broken pottery relics
XIE Lina, LI Yuhu*, WANG Shenglin, BAI Chongbin
(Engineering Research Center of Historical Cultural Heritage Conservation, Ministry of Education, Shaanxi Normal University, Xi′an 710119, Shaanxi, China)
Abstract:
An inorganic modified phosphate adhesive for repairing fractured pottery relics was developed, and the comparison in adhesion between the modified phosphate and commonly used epoxy resin was investigated. After hygrothermal aging and dry heat aging, the adhesive strength,micro-morphology and FTIR were determined to evaluate adhesive performance, the breathability, water permeability and SEM were used to evaluate compatibility between adhesive and pottery body. The tests of breathability and water permeability and SEM are to evaluate the compatibility between adhesive and pottery body. The results revealed that inorganic modified phosphate adhesive with strong anti-aging properties and good compatibility is a novel and approving material for pottery preservation.
KeyWords:
pottery relics; bonding; adhesive; anti-aging property; compatibility