自然科学版
陕西师范大学学报(自然科学版)
化学与材料科学
温度-磁性双重敏感性复合纳米催化剂Fe3O4@Ag/P(NIPAM-co-MPTMS)的合成及性能
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姜春阁, 范颖兰, 张颖*
(应用表面与胶体化学教育部重点实验室,陕西师范大学 化学化工学院,陕西 西安 710119)
张颖,女,教授,博士生导师,主要从事胶体界面化学方面的研究工作。E-mail: zhangy@snnu.edu.cn
摘要:
以负载纳米银粒子的Fe3O4@Ag异质结构为核,N-异丙基丙烯酰胺(NIPAM)和3-(甲基丙烯酰胺)丙基三甲氧基硅烷(MPTMS)为单体,通过乳液聚合法得到Fe3O4@Ag/P(NIPAM-co-MPTMS)有机-无机复合材料。通过透射电子显微镜(TEM)、X-射线光电子能谱(XPS)、X射线衍射(XRD)仪、热分析(TGA)和紫外-可见(UV-Vis)分光光度计等手段对Fe3O4@Ag/P(NIPAM-co-MPTMS)有机-无机复合材料的结构、组成和性质进行表征。研究结果表明,通过调节银氨溶液初始浓度可控制纳米银的分散性,且有机-无机杂化网络壳层厚度可通过单体的加入量进行调节。该复合纳米催化剂具有较高的催化活性、温度可调控性和重复使用性。
关键词:
磁性纳米粒子;纳米银;敏感性;复合纳米催化剂;对硝基苯酚还原
收稿日期:
2018-03-19
中图分类号:
Q948.11
文献标识码:
A
文章编号:
1672-4291(2019)04-0076-08
基金项目:
国家自然科学基金(21173141);陕西省自然科学基金(2019JM-500)
Doi:
Synthesis and properties of temperature-magnetic dual-sensitive composite nanocatalysts Fe3O4@Ag/P(NIPAM-co-MPTMS)
JIANG Chunge, FAN Yinglan, ZHANG Ying*
(Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education; School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi′an 710119, Shaanxi, China)
Abstract:
The Fe3O4@Ag/(N-isopropylacrylamide-co-3-methacryloxy propyl trimethoxy silane)(Fe3O4@Ag/P(NIPAM-co-MPTMS)) organic-inorganic composite materials were synthesized through seed-emulsion polymerization method, using Fe3O4@Ag nanoparticles as cores, NIPAM and MPTMS as monomers. The technologies of transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, thermogravimetric analysis and UV-Visible spectroscopy were used for analyzing the structure, composition and properties of the prepared Fe3O4@Ag/P(NIPAM-co-MPTMS) materials. It was demonstrated that the dispersity of Ag nanoparticles, loaded on the Fe3O4 nanoparticles, could be regulated by adjusting the initial concentration of silver-ammonia solution. The thickness of the shell of the organic-inorganic hybrid network can be adjusted by the amount of monomer. Furthemore, the Fe3O4@Ag/P(NIPAM-co-MPTMS) composite materials exhibit excellent catalytic activity, temperature sensitivity and reusability.
KeyWords:
magnetic nanoparticles; Silver nanoparticles; sensitivity; composite nanocatalysts; reduction of 4-nitrophenol