自然科学版
陕西师范大学学报(自然科学版)
合成气定向催化转化科学与技术专题
蒙古国煤水蒸气气化制合成气及其热力学特性
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李娜, 刘鲁峰, 张楹斗, 刘全生*
(内蒙古工业大学 化工学院,内蒙古低阶碳质资源高值功能化利用重点实验室, 内蒙古 呼和浩特 010051)
刘全生,男,教授,博士生导师,主要从事煤炭化工方面的研究。E-mail: liuqs@imut.edu.cn
摘要:
对来自蒙古国不同地区的4种煤样的水蒸气气化性能进行系统研究,考察了4种煤样水蒸气气化合成气的组成与生成规律;讨论了热力学平衡对4种煤样气化反应的影响。研究发现,巴嘎诺尔煤(BN)、纳赖呼煤(NL)和阿拉格陶盖煤(AT)的水蒸气气化反应性能明显高于塔本陶勒盖煤(TT)。BN、NL和AT煤可通过水蒸气气化反应制高H2含量、低CO含量的合成气,而TT煤水蒸气气化合成气中CO的含量相对较高。造成这种现象的原因是BN、NL和AT煤气化过程中水煤气变化反应(WGSR)进行的较为彻底,消耗了煤与水蒸气直接气化反应所生成的CO,生成更多的H2,而TT煤WGSR进行程度较低,故其合成气中CO含量较高,因此认为热力学平衡是造成不同种类蒙古国煤水蒸气气化特性存在差异的重要因素。
关键词:
蒙古国煤;水蒸气气化;合成气;热力学
收稿日期:
2018-10-23
中图分类号:
TQ564
文献标识码:
A
文章编号:
1672-4291(2019)01-0087-07
基金项目:
国家自然科学基金(21868021, 21566029, 21676149);内蒙古自然科学基金(2018BS02007, 2017MS0201)
Doi:
Syngas produced by steam gasification of Mongolia coals and its thermodynamic characteristics
LI Na, LIU Lufeng, ZHANG Yingdou, LIU Quansheng*
(School of Chemical Engineering,Inner Mongolia University of Technology,Inner Mongolia Key Laboratory of High-Value Functional Utilization of Low Rank Carbon Resource,Huhhot 010051, Inner Mongolia, China)
Abstract:
Steam gasification of coal is one of the efficient ways to produce syngas from coal. Steam gasification performance of four kinds of Mongolia coal was comprehensively investigated in this paper. The composition and the evolution rates of syngas were studied during steam gasification. The influence of thermodynamic equilibrium on the gasification reaction of four coal samples was also discussed. As research shown that the steam gasification performance of Baganuur coal (BN), Nalaik coal (NL) and Alagtogoo coal (AT) were significantly higher than that of Tawantolgoi coal (TT). The syngas contained high H2 and low CO contents producing by BN, NL and AT, however, TT produced the syngas which contain high CO content, since the water-gas shift reaction (WGSR) was carried out completely with high H2 and low CO production rates in steam gasification process of BN, NL and AT. Syngas of high CO content was produced from steam gasification of TT due to its low WGSR. Moreover, the thermodynamic equilibrium was one of the main factors led to the differences of steam gasification characteristics for the four kinds of Mongolia coal.
KeyWords:
Mongolia coals; steam gasification; syngas; thermodynamics