自然科学版
陕西师范大学学报(自然科学版)
合成气定向催化转化科学与技术专题
催化材料的成型及力学性能研究
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徐晓颖1, 胡雯霞1,2, 韩志华1 , 张玉龙1*
(1 北京低碳清洁能源研究院 煤化工研究中心, 北京 102211;2 北京理工大学 宇航学院, 北京 100081)
张玉龙,男,主任工程师,主要从事合成气转化高附加值化学品方面的研究。E-mail: zhangyulong@nicenergy.com
摘要:
催化材料在工业生产中应用广泛,90%以上的化工产品都是通过催化反应制备出来的,而催化反应的关键就是催化材料,俗称催化剂。其中,应用到多相反应中的工业催化剂,因对机械强度有较高的要求,需将其原粉成型至特定几何形状、尺寸后使用,以便抵挡反应过程中因应力变化造成的冲击。成型方法、工艺条件、成型后颗粒的标准化机械强度测试,以及系统分析催化材料的力学性能,是催化剂生产中的关键环节。本文主要论述了催化材料的种类、成型方式、强度测试方法、力学性能分析,以及成型样品缺陷表征手段,并结合数据展示图,介绍了一种新兴的断层扫描(MicroCT)样品无损表面缺陷表征手段。
关键词:
催化剂; 成型; 力学性能; 强度测试; 缺陷表征
收稿日期:
2018-10-31
中图分类号:
TP391.42
文献标识码:
A
文章编号:
1672-4291(2019)01-0038-06
基金项目:
国家重点研发计划(2018YFB0604500);北京低碳清洁能源研究院资助(CF9300162131)
Doi:
Research on the forming of catalyst materials and their mechanical property
XU Xiaoying1, HU Wenxia1,2, HAN Zhihua1, ZHANG Yulong1*
(1 National Institute of Clean-and-Low Carbon Energy, Coal Chemical Technology Center, Beijing 102211, China;2 Beijing Institute of Technology, School of Aerospace Engineering, Beijing 100081, China)
Abstract:
Catalyst materials are widely used in industry and nearly 90% of the chemical products were produced via catalysis. Among heterogeneous catalysis, catalysts must have strong mechanical strength in order to stand for the dynamic changes of mechanical stress that might occur during reactions. Thus, to optimize the forming technology and processing parameters, the ways to characterize mechanical strength of each particle are very important for large-scale catalyst preparation. Herein, this paper clarified the type of catalysts, the way for powder forming, characterization methods for the formed catalyst and the methods to detect the strength and defects of formed catalysts. Meanwhile, it also demonstrated a novel defect detection tool (MicroCT) with recorded pictures.
KeyWords:
catalyst; catalyst forming; mechanical property; strength testing; MicroCT