自然科学版
陕西师范大学学报(自然科学版)
化学与材料科学
RGO/TiO2/Fe3O4复合纳米材料的制备及其对甲基橙废水的脱色效果
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王宇航
(陕西学前师范学院 化学与化工系, 陕西 西安 710100)
王宇航,女,讲师,博士研究生,研究方向为无机功能材料。E-mail:yuhangwang0912@163.com
摘要:
通过水热法制备Fe3O4磁性纳米微球,以此为核包覆TiO2,并将核壳结构的TiO2/Fe3O4附着在还原氧化石墨烯(RGO)片层结构上;利用扫描电镜(SEM)、透射电镜(TEM)、N2吸附-脱附、X射线衍射仪(XRD)、震动样品磁强计(VSM)和X射线光电子能谱(XPS)表征了RGO/TiO2/Fe3O4磁性复合纳米材料的形态结构、包覆情况、磁性和元素种类,同时考察了该催化剂在紫外光照射下催化脱色甲基橙的效果。实验结果表明,TiO2均匀地包覆在Fe3O4表面,RGO/TiO2/Fe3O4磁性复合纳米材料的比饱和磁化强度为19.0 emu/g。以甲基橙的水溶液为模拟污染物,紫外光照射90 min后RGO/TiO2/Fe3O4复合纳米材料对甲基橙的脱色率达到91%。
关键词:
光催化剂;磁性;RGO/TiO2/Fe3O4; 甲基橙
收稿日期:
2017-12-30
中图分类号:
TP331;X791
文献标识码:
A
文章编号:
1672-4291(2018)04-0058-06
基金项目:
陕西省自然科学基础研究计划(2014JQ6203);化学省级实验教学示范中心建设项目
Doi:
The synthesis of RGO/TiO2/Fe3O4 nanocomposites and its photo-catalysis in degradation of methyl orange
WANG Yuhang
(Department of Chemistry and Chemical Engineering, Shaanxi Xueqian Normal University, Xi′an 710100, Shaanxi,China)
Abstract:
The magnetic Fe3O4 nanoparticles were successfully prepared through hydrothermal method, then TiO2 was coated as the shell of the magnetic nanoparticles. Finally, the core-shell structural TiO2/Fe3O4 nanoparticles were adhered on the layer of RGO surface. The morphological feature, magnetism and elemental composition of the RGO/TiO2/Fe3O4 photocatalyst were characterized with SEM,TEM, N2 adsorption-desorption, XRD, VSM and XPS analysis. The photo-catalysis of the prepared structural nanoparticles in degradation of methyl orange was investigated. The results indicated that TiO2 were dispersed uniformly on the Fe3O4 core nanoparticle surface. In addition, the saturation magnetization of the RGO/TiO2/Fe3O4 nanoparticles was 19.0 emu/g, and the photocatalytic decolorization ratio for methyl orange was up to 91% after 90 min of UV irradiation.
KeyWords:
photocatalyst; magnetism; RGO/TiO2/Fe3O4; methyl orange