自然科学版
陕西师范大学学报(自然科学版)
化学与材料科学
有机材料NPB纳米点阵列的制备及其场发射性能
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徐春龙1*, 王真1, 左亚路2, 席力2, 石国杰1
(1 长安大学 理学院, 陕西 西安 710064; 2 兰州大学 磁学与磁性材料教育部重点实验室, 甘肃 兰州 730000)
徐春龙,男,副教授,博士。E-mail:chunlongxu@chd.edu.cn
摘要:
通过真空热蒸发法制备了N,N′-二苯基-N,N′-(1-萘基)-1,1′-联苯-4,4′-二胺(N,N′-Di-\[(1-naphthalenyl)-N,N′-diphenyl\]-1,1′-biphenyl)-4,4′-diamine; NPB)纳米点阵列。通过AFM和SEM对其形貌进行了表征。在高真空下,利用循环测试法测量了样品的场发射性能,其开启电场和阈值电场值分别为4.5和15 V/μm,最大电流密度可达1.68 mA/cm2。同时,随着测试电场循环升高降低,相应的电流密度曲线出现了明显的滞后,这主要是由于在高真空下样品表面小分子气体的吸附/去吸附效应导致样品的功函数发生变化。长时间测试结果表明,NPB纳米点阵列的场发射性能表现出了良好的稳定性。
关键词:
NPB; 热蒸发法; 纳米点阵列; 场发射
收稿日期:
2016-03-01
中图分类号:
N27; O462. 4
文献标识码:
A
文章编号:
1672-4291(2016)04-0056-04doi:10.15983/j.cnki.jsnu.2016.04.341
基金项目:
国家自然科学基金(51171076,51101079); 中央高校基本科研业务费专项资金 (310812151002)
Doi:
Field emission properties of NPB nanodot arrays
XU Chunlong1*, WANG Zhen1, ZUO Yalu2, XI Li2, SHI Guojie1
(1 Department of Applied Physics, Chang′an University, Xi′an 710064, Shaanxi, China; 2 Key Laboratory for Magnetism and Magnetic Materials of Ministry of Education, Lanzhou University, Lanzhou 730000, Gansu, China)
Abstract:
A thermal evaporation method in high vacuum has been developed to synthesize N,N′-Di-\[(1-naphthalenyl)-N,N′-diphenyl\]-1,1′-biphenyl)-4,4′-diamine (NPB) nanodot arrays. The morphology of the sample was investigated with SEM and AFM. A cycle-testing of field emission behavior was carried out for NPB nanoarrays. The field-emission characteristics of the nanodot arrays exhibit that turn-on field is 4.5 V/μm, the threshold field is 15 V/μm and a maximum current density is 1.68 mA/cm2. A obvious hysteresis in the cycle testing with continuous rising and falling current density was observed in the case of the considered samples, which can be attributed to microstructure and adsorption/desorption effect.It is shown that the NPB nanodot arrays showed good current stability in a long time test.
KeyWords:
N,N′-Di-\[(1-naphthalenyl)-N,N′-diphenyl\]-1,1′-biphenyl)-4,4′-diamine (NPB); thermal evaporation; nanodot arrays; field emission