自然科学版
陕西师范大学学报(自然科学版)
化学与材料科学
溴化1-癸基-3-甲基咪唑离子液体+脂肪醇二元溶剂体系的物理化学性质
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张云霞, 李淑妮*, 翟全国, 蒋育澄,胡满成
(陕西师范大学 化学化工学院, 陕西 西安 710119)
张云霞,女,硕士研究生,研究方向为溶液化学。E-mail:291085679@qq.com
摘要:
在大气压力0.1 MPa及288.15~308.15 K温度下测定了溴化1-癸基-3-甲基咪唑离子液体(\[C10mim\]Br)+脂肪醇{乙二醇(EG)/ 1, 2-丙二醇(PG)/ 正丙醇(NPA)}三个二元体系的密度(ρ)、折光率(nD)和黏度(η)。计算获得了过量摩尔体积(VEm)和折光率偏差(ΔnD),并用Redlich-Kister方程对衍生性质数据进行拟合。密度、折光率和黏度值随组成的变化用多项式方程进行了拟合。通过对实验数据的比较,总结出脂肪醇的碳链长度和羟基个数以及温度等对物化性质的影响。
关键词:
溴化1-癸基-3-甲基咪唑离子液体; 脂肪醇; 密度; 黏度; 折光率
收稿日期:
2015-03-06
中图分类号:
TP391.42
文献标识码:
A
文章编号:
1672-4291(2015)06-0043-06doi:10.15983/j.cnki.jsnu.2015.06.361
基金项目:
国家自然科学基金(21171111, 21271123, 21301114);陕西省自然科学基金(2013JQ2009)
Doi:
Physicochemical properties of binary mixtures {\[C10mim\]Br + alcohol}
ZHANG Yunxia, LI Shuni*, ZHAI Quanguo, JIANG Yucheng, HU Mancheng
(School of Chemistry and Chemical Engineering, Shaanxi Normal University,Xi′an 710119, Shaanxi, China)
Abstract:
The density(ρ), refractive index(nD), and dynamic viscosity(η), for the three binary solutions containing 1-decyl-3-methylimidazolium bromide(\[C10mim\]Br) and fatty alcohol{ethylene glycol (EG), 1,2-propanediol (PG), and 1-propanol (NPA)} were investigated,respectively at temperatures of 288.15~308.15 K and under ambient pressure.Additionally, the excess molar volume(VEm),and deviation of the refractive index(ΔnD), were calculated and correlated using the Redlich-Kister polynomial equation. The variation of density,refractive index and viscosity with the composition was described by the polynomial equations. The influence of carbon-chain length and the hydroxyl number of the fatty alcohol, and the influence of the temperature on the physicochemical properties of the binary systems can be explained by the comparison of the experimental results.
KeyWords:
1-decyl-3-methylimidazoliumbromide; fatty alcohol; density; viscosity; refractive index