自然科学版
陕西师范大学学报(自然科学版)
化学与材料科学
西安明城墙砖石表面风化因素分析
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赵光涛1, 李玉虎1*, 张译丹1, 杜德新2
(1 陕西师范大学 材料科学与工程学院, 陕西 西安 710119;2 西安唐皇城墙含光门遗址博物馆, 陕西 西安 710069)
赵光涛,男,博士研究生,主要研究方向为文物保护。E-mail:532829877@qq.com
摘要:
对西安明城墙实地风化现状进行考察,发现城墙表面存在大面积白色盐析现象,这不仅影响城墙整体美感,更会造成古砖表面风化。通过对墙体表面析出盐分进行X射线衍射(XRD)、扫描电镜(SEM)及离子色谱分析(IC), 研究了其风化产生的原因。结果表明,其墙体表面析出盐的主要成分为硫酸钠,硫酸钠对于砖质文物具有严重的侵蚀作用。在实验室进行模拟实验基础上,结合硫酸钠对砖体的侵蚀机理,对造成的风化现象进行了分析。
关键词:
明城墙; 风化; 可溶盐; 文化遗产保护
收稿日期:
2014-11-03
中图分类号:
K878
文献标识码:
A
文章编号:
1672-4291(2015)04-0054-05doi:10.15983/j.cnki.jsnu.2015.04.341
基金项目:
国家社会科学基金(10XZS013)
Doi:
Analysis of the factors in masonry surface weathering of Ming Dynasty City Wall in Xi′an
ZHAO Guangtao1, LI Yuhu1*, ZHANG Yidan1, DU Dexin2
(1 School of Materials Science and Engineering, Shaanxi Normal University, Xi′an 710119, Shaanxi, China;2 Xi′an Museum of Hanguang Entrance of Tang Imperial City,Xi′an 710069, Shaanxi, China)
Abstract:
In surveying the weathered surface appearance on Xi′an Ming Dynasty City Wall, the white salt powders were largely found on the surface of the bricks, which greatly affect overall appearance and cause bricks into pulverization. To reveal the reasons, we analyzed the soluble salts from the surface of bricks by using X-ray diffraction(XRD), scanning electron microscopy(SEM) and ion chromatography(IC). The results showed that the main component of the soluble salt is sodium sulfate. According to the corrosion mechanism related to sodium sulfate, some simulated experiments were carried out in the laboratory, and the weathering phenomenon caused by soluble salt was investigated.
KeyWords:
The Ming Dynasty City Wall; the weathering; soluble salt; cultural heritage conservation