自然科学版
陕西师范大学学报(自然科学版)
化学与材料科学
H2O2协同作用下的多通道光催化反应体系研究
PDF下载 ()
王常顺1,2, 佘江波2, 张国防1*
(1 应用表面与胶体化学教育部重点实验室, 陕西师范大学 化学化工学院, 陕西 西安 710119;2 瞬态光学与光子技术国家重点实验室,中国科学院 西安光学精密机械研究所, 陕西 西安 710119)
王常顺,男,硕士研究生,研究方向为先进光电功能材料. E-mail:changshun6@sina.com.
摘要:
使用具有547个孔道的微结构聚合物预制棒,建立了一种新型的光催化降解有机废水体系.通过微波热处理技术,TiO2纳米晶薄膜附着在光催化反应体系的孔道中.使得反应体系增加光催化剂和溶液的接触面积,提高了光催化效率,同时加入强氧化剂H2O2来协同TiO2用于光催化分解有机染料罗丹明B;研究了H2O2的浓度及RB的初始浓度对光催化的影响,表明该反应体系在光照的条件下具有降解有机染料的能力.
关键词:
光催化; 微结构聚合物光纤二次预制棒; 二氧化钛; 罗丹明B
收稿日期:
2014-02-11
中图分类号:
O643.32; TN253
文献标识码:
A
文章编号:
1672-4291(2014)04-0045-05
基金项目:
国家自然科学基金资助项目(61108061, 21171112).
Doi:
The research of the photocatalytic reaction system with multi-channel array under the synergistic effect of H2O2
WANG Changshun1,2, SHE Jiangbo2, ZHANG Guofang1*
(1 Key Laboratory of Applied Surface and Colloid Chemistry, MOE/College of Chemistry andChemical Engineering, Shaanxi Normal University, Xi′an 710119,Shaanxi, China 2 State Key Laboratory of Transient Optics and Photonics, Xi′ an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences, Xi′an 710119, Shaanxi, China)
Abstract:
A new type of photocatalytic degradation of organic wastewater system based on microstructured polymer optical fiber (MPOF) preform with 547 pores was designed, constructed, and each channel was covered with TiO2 film. The photocatalytic active TiO2 nanocrystal film that covered on the channels of the MPOF preform was obtained by microwave processing. Thus the inner surfaces of pores, used as the reactors for the photocatalyst,was expected to increase the photocatalyst - liquid contact area, and enhance the photocatalytic efficiency. Moreover, hydrogen peroxide was added as strong oxidant to synergy degradating Rhodamine B in solution. The effects of different initial hydrogen peroxide concentration and the dye concentration were investigated.The results indicated that the photocatalysis activity of the system was proved to possess the ability of degradating organic dye in the light.
KeyWords:
photocatalysis; microstructured polymer optical fiber preform; titanium dioxide; Rhodamine B