自然科学版
陕西师范大学学报(自然科学版)
物理学
BFO含量对Bi (Mg1/2Ti1/2)O3-PbTiO3-xBiFeO3陶瓷结构和性能的影响
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晁波, 刘鹏*, 赵小刚, 刘苏娟
(陕西师范大学 物理学与信息技术学院, 陕西 西安 710119)
晁波,男,硕士研究生.研究方向为高温压电陶瓷.E-mail:chaobo0829@163.com.
摘要:
采用传统的电子陶瓷的制备方法,以铁酸铋(BFO)为掺杂原料,在不同掺杂量制备了Bi (Mg1/2Ti1/2)O3-PbTiO3-xBiFeO3陶瓷.使用X射线衍射仪、介电温谱测试系统、环境扫描电镜、准静态d33测量仪对样品进行表征,结果表明:准同型相界附近的陶瓷试样中,随着烧结温度升高,密度降低,并且在1 075 ℃烧结温度下,不同BFO含量的样品均形成单一的钙钛矿(ABO3)型固溶体结构.BFO的掺杂能够有效降低粉末的平均颗粒尺寸,普通球磨的粉体添加x=0.015 mol BFO在1 075 ℃烧结的样品表现出较为优秀的铁电性能.
关键词:
高居里温度; 介电性能; 压电性能
收稿日期:
2013-09-29
中图分类号:
O482.41; O482.53
文献标识码:
A
文章编号:
1672-4291(2014)04-0033-05
基金项目:
国家自然科学基金资助项目(51072110); 中央高校基本科研业务费专项资金项目(GK201104008,GK201305006).
Doi:
BFO content-influence on the structure and properties of theBi (Mg1/2Ti1/2)O3-PbTiO3-xBiFeO3 ceramics
CHAO Bo, LIU Peng*, ZHAO Xiaogang, LIU Sujuan
(College of Physics and Information Technology,Shaanxi Normal University, Xi′an 710119,Shaanxi, China)
Abstract:
Ceramic with the chemical compositions of Bi(Mg1/2Ti1/2)O3-PbTiO3-xBiFeO3 (BMT-PT-xBFO) piezoelectric ceramic were prepared by conventional solid-state reaction method.The samples were tested and characterized by X-ray diffraction (XRD),dielectric temperature spectrum test system,environment scanning electron microscopy(SEM),quasi-static d33 meter. The results show that the density of samples decrease with sintering temperature.When sintering temperature is 1 075 ℃,different amount of BFO samples form a single perovskite structure (ABO3) solid solution. BiFeO3 doping can effectively reduce the average particle size of powder.It can be found that the BMT-PT ceramics obtained with 0.015 mol BiFeO3 addition and sintered at 1 075 ℃ show excellent performance relatively.
KeyWords:
high curie temperature; dielectric properties; piezoelectric properties