自然科学版
陕西师范大学学报(自然科学版)
生命科学
黄连木果油制备生物柴油的应用研究
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宋双红,陈康健,王喆之*
(药用资源与天然药物化学教育部重点实验室, 西北濒危药材资源开发国家工程实验室, 陕西师范大学 生命科学学院,陕西 西安 710062)
宋双红,女,博士研究生,研究方向为植物生物技术.E-mail:songshuanghong@snnu.edu.cn.
摘要:
提取黄连木果油并以此为原料,通过碱催化酯交换法制备生物柴油,采用单因素实验和L9(34)正交实验确定酯交换最佳工艺条件,并对所得生物柴油进行成分分析和理化性能检测.实验表明:以石油醚为溶剂,超声提取35 min,黄连木果油得率可达到50%以上.所得黄连木果油制备生物柴油的最佳工艺条件为:醇油摩尔比4∶1,催化剂用量为1.6 %,反应时间60 min,反应温度40 ℃,转化率可达到98.74%.它与0#柴油的主要性能指标相接近,可以考虑按一定的比例调入柴油中使用.
关键词:
黄连木; 气质联用; 生物柴油
收稿日期:
2012-12-18
中图分类号:
Q274
文献标识码:
A
文章编号:
1672-4291(2013)06-0063-05
基金项目:
“十二五”国家科技支撑计划项目(2011BAI06B06).
Doi:
Research on extraction of Pistacia chinensis seed oil and the process of biodiesel production
SONG Shuang-hong, CHEN Kang-jian, WANG Zhe-zhi*
(Key Laboratory of Medicinal Resources and Natural Pharmaceutical Chemistry of the Ministry of Education, National Engineering Laboratory for Resource Developing of Endangered Chinese Crude Drugs in Northwest of China, College of Life Sciences, Shaanxi Normal University, Xi′an 710062, Shaanxi, China)
Abstract:
To extract the seed oil of Pistacia chinensis and to optimize the technological parameters for preparing biodiesel,in the presence of the catalyst, biodiesel was synthesized from Pistacia Chinensis seed oil by transesterification, the optimum conditions of transesterification was obtained by L9(34) orthogonal experiments. The main constituents and physico-chemical performance of biodiesel was determined. The results show that using petroleum ether as solvent and ultrasonic extraction 35 min, the oil yield can reach more than 50%.The optimum reaction conditions are as follows: molar ratio of alcohol to oil is 4∶1, mass ratio of the catalyst to the oil is 1.6%, reaction time and reaction temperature are 60 min and 40 ℃,respectively. Under the conditions, the yield of biodiesel was 98.74%. The performance of the produced biodiesel is coloses to No.0 diesel.
KeyWords:
Pistacia chinensis Bunge; GC-MS; biodiesel