自然科学版
陕西师范大学学报(自然科学版)
物理学
铝膜表面周期性纳米坑织构的制备
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宋美周1, 2, 高斐2*, 刘生忠2, 3,李宁1, 刘晓静2, 杨波2
(1 陕西师范大学 物理与信息技术学院, 2 材料科学与工程学院,3 应用表面与胶体化学教育部重点实验室, 陕西 西安710062)
宋美周,男,硕士研究生,研究方向为光伏薄膜材料.E-mail:381755465@qq.com.
摘要:
采用一次阳极氧化铝的方法分别在草酸、磷酸和柠檬酸溶液中制备了多孔阳极氧化铝膜,腐蚀掉铝片表面的氧化铝膜,铝片表面留下周期性纳米坑织构.利用扫描电子显微镜分析不同阳极氧化条件下铝膜的表面形貌,结果表明:铝片表面有序的六角阵列的纳米坑形成,坑的孔径大小随阳极氧化电压的升高而增大.铝片阳极氧化电压为300 V,在浓度为4%柠檬酸中氧化2 h,坑孔径达到785 nm.使用光散射仪测量样品的光散射谱并研究样品对光的散射特性,散射光的强度随着散射角的增大而减小,铝膜表面纳米坑孔径越大对光散射越强.
关键词:
多孔氧化铝膜; 阳极氧化; 铝纳米坑; 光散射
收稿日期:
2013-03-28
中图分类号:
TM914
文献标识码:
A
文章编号:
1672-4291(2013)06-0038-04
基金项目:
国家自然科学基金资助项目(61040057); 香港何崇本新能源基金资助项目; 中央高校创新基金资助项目(GK201101003).
Doi:
The fabrication of Al surface texture of periodic nano-pits
SONG Mei-zhou1,2, GAO Fei2﹡, LIU Sheng-zhong2,3,LI Ning1, LIU Xiao-jing2 ,YANG Bo2
(1 College of Physics and Information Technology,2 College of Materials Science and Engineering, Shaanxi Normal University,3 Key Laboratory of Applied Surface and Colloid Chemistry, MOE, Shaanxi Normal University, Xi′an 710062, Shaanxi, China)
Abstract:
Al surface periodic nanp-pits have been fabricated by anodizing Al foils in oxalic acid, phosphoric acid, and citric acid solution, and etching away the porous anodic aluminum film. Surface morphology of the fabricated Al nanp-pits was studied by scanning electron microscopy(SEM) and the results show that ordered hexagonal array of nano-pits formed on the surface of the Al foils. Average size of the Al nanp-pits increases with increasing anodizing voltage. When anodizing voltage is 300 V, with 4% citric acid and oxidation time of 2 h, the average size of the Al nanp-pits reaches to 785 nm. The light scattering properties of the fabricated Al nanp-pits were studied by light-scattering instrument. The intensity of scattered light decreases with increasing scattering angle, and the larger Al nanp-pits have stronger light scattering.
KeyWords:
porous alumina membrane; anodizing; Al nano-pit; light scattering