自然科学版
陕西师范大学学报(自然科学版)
化学与材料科学
电化学氧化法对模拟废水中茜素红染料脱色的研究
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郑博, 马红竹*, 王博
(陕西师范大学 化学化工学院, 陕西 西安 710062)
郑博,男,硕士,研究方向为废水处理.E-mail:zhengbonba@sina.com.
摘要:
采用电化学氧化法,以石墨作阳极钛网作阴极并用硫酸改性的活性白土为催化剂,在500 mL的电解槽中对蒽醌染料废水茜素红的电化学氧化进行了研究.探讨了初始pH、外加电压、电解质种类、通气量、以及染料初始浓度对茜素红脱色的影响.实验结果表明:在室温下电解50 min、浓度为200 mg/L、pH为3、槽电压为10 V、电解质为3 g/L的氯化钠、催化剂为20 g/L、通气量为100 L/h时,染料废水的脱色率能够达到97.1%.
关键词:
电化学氧化法; 茜素红; 酸化活性白土; 脱色
收稿日期:
2012-04-11
中图分类号:
X703.1
文献标识码:
A
文章编号:
1672-4291(2013)05-0055-05
基金项目:
中央高校基本科研业务费专项资金项目(GK201302013).
Doi:
Research on decolorization of simulated wastewater containing alizarin red S dye by electrochemical oxidation
ZHENG Bo, MA Hong-zhu*, WANG Bo
(College of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi′an 710062, Shaanxi, China)
Abstract:
The electrochemical oxidation of anthraquinone dye alizarin red S in simulated wastewater was investigated. In this method, sulfuric acid-modified activated clay was used as catalyst,the graphite plate and titanium net were used as anode and cathode respectively. The effects of initial pH, applied voltage, electrolyte type, ventilation, and the initial dye concentration on decolorization of alizarin red S were studied. From the results, it can be found that decolorizing rate could reach up to 97.1% in 50 min.In case of the initial pH at 3, concentration of 200 mg/L, 3 g/L of sodium chloride, cell voltage at 10 V, 20 g/L catalyst, ventilation at 100 L/h.
KeyWords:
electrochemical oxidation; alizarin red S; acid activated clay; decolorization