自然科学版
陕西师范大学学报(自然科学版)
食品胶体与物性调控专题
魔芋葡甘聚糖的功能化改性及应用
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廖晴雨,张洪斌*
(上海交通大学 流变学研究所,高分子科学与工程系,变革性分子前沿研究中心,上海 200240)
张洪斌,男,教授,博士生导师,研究方向为天然高分子物理化学和流变学。E-mail:hbzhang@sjtu.edu.cn
摘要:
魔芋葡甘聚糖(konjac glucomannan, KGM),也称魔芋胶,是从魔芋块茎中提取的中性杂多糖。KGM长期以来被作为增稠剂、凝胶剂,广泛应用于食品、医药、化工等领域,是高效的质构改良剂和流变学性质调节剂。然而,天然KGM水溶性低、加工性能差,采用化学和物理改性是提高其水溶性、发掘新功能和拓展新应用的有效手段。因此,系统综述了KGM的各类改性方法以及未改性和改性产物在乳液、凝胶、膜材料、生物医用材料、食品及营养健康等领域的应用,着重总结了近年来KGM的酯化、酰基化、羧甲基化、磺化、氧化、阳离子化、接枝共聚交联等化学改性,共混填充、物理交联、微流控纺丝、γ射线辐照等物理改性的研究进展及改性产物的应用进展,指出了KGM未来研究的发展趋势以及存在的问题和挑战。
关键词:
魔芋葡甘聚糖;功能化;化学改性;物理改性;生物活性;应用
收稿日期:
2022-03-09
中图分类号:
O629
文献标识码:
A
文章编号:
1672-4291(2022)05-0064-17
基金项目:
国家自然科学基金(22073062)
Doi:
10.15983/j.cnki.jsnu.2022020
Functional modification and application of konjac glucomannan
LIAO Qingyu,ZHANG Hongbin*
(Advanced Rheology Institute, Department of Polymer Science and Engineering,Frontiers Science Center for Transformative Molecules,Shanghai Jiao Tong University, Shanghai 200240, China)
Abstract:
Konjac glucomannan (KGM) is a kind of neutral heteropolysaccharide extracted from konjac tubers. KGM has been widely used in food, medicine, chemical industry and other fields as thickener and gel agent for a long time.It is a highly efficient texture modifier and rheological property regulator. However, the application of natural KGM is limited due to its low water solubility and poor processability. Chemical and physical modifications are effective approaches to overcome these limitations, thereby developing new functionalities and expanding its new applications. In this review, various modification methods of KGM and the applications of unmodified and modified products in emulsion, gel, membrane materials, biomedical materials, food, nutrition and health fields were comprehensively summarized. Recent progress on chemical modifications of KGM such as esterification, deacetylation, carboxymethylation, sulfonation, oxidation, cationization and graft copolymerization, and physical modifications including blending filling, physical crosslinking, microfluidic spinning and γ irradiation were highlighted and holistic discussed. Furthermore, the future trend as well as some problems and challenges in the research and development of KGM were pointed out.
KeyWords:
konjac glucomannan; functionalization; chemical modification; physical modification; bioactivity; application